The list will name those who have racked up more than $1,000 in tolls and fines, officials said.
"We are working to compile this list now and hope to be able to publish it on the Tollway's website this week," agency spokeswoman Wendy Abrams said.
The Tollway's action follows similar public shamings by agencies in Texas and on the East Coast.
Another agency that uses the tactic is the Port Authority of New York and New Jersey. Its "Wall of Shame" lists the "top egregious toll violators."
Last year the Illinois Tollway estimated that deadbeats had racked up about $300 million in unpaid tolls and fines since 2001.
The Tollway said it issues about 1.4 million first-violation notices every year. The agency collected more than $33 million in revenue from toll violations in 2011, according to a recent audit.